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Acute toxicity: Methamidophos is highly toxic via oral, dermal and inhalation routes of exposure. 3 For methamidophos (USEPA/OPP Pesticide Code: 101201) ACTIVE products with label matches. USA.gov. 0000003144 00000 n
The resistant individuals can eventually dominate the insect population if these insecticides … CROP PESTRATEREMARKS Potatoes Aphids 800ml/ha Apply at first appearance in 500-1000 litres of water/hectare repeating … Alexander Drive Research Triangle PK, NC 27709 USA Current sources of methamidophos include environmental degradation or metabolism of acephate. It was used mainly on commercial crops of potatoes, cotton, and tomatoes, had limited use in commercial and public buildings, but it was not registered for any residential uses. Office of Response and Restoration, National Oceanic and Atmospheric Administration. endstream
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Avoid strong acids or alkalis. AGRICULTURAL USE REQUIREMENTS Use this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. Methamidophos (O,S-dimethyl phosphoramidothioate) is a non-systemic organophosphorus insecticide and acaricide used to control a variety of horticultural and agricultural pests. Stable at neutral pH. 0000001074 00000 n
Used as an insecticide on a number of vegetables and on cotton. OF ACEPHATE AND METHAMIDOPHOS PRODUCTS IN THE SAME SEASON ON THE SAME CROPS SHOULD BE AVOIDED TO ENSURE COMPLIANCE WITH MAXIMUM RESIDUE LIMITS. It is particularly effective against chewing and sucking insects and is used to control aphids, flea beetles, worms, whiteflies, thrips, cabbage loopers, Colorado potato beetles, potato tubeworms, armyworms, mites, leafhoppers, and many others. Application of methamidophos products after application of acephate may result in illegal residues. Patrole, Tamanox, SRA 5172, and Tam (156, 13). Contact us on 087 740 3490 for more information: View MSDS: Dusting Sulphur (UCP) Fungicide 980 DP: sulphur inorganic: M2: L5261: N-AR 0991 To delay insecticide resistance: Avoid exclusive repeated use of insecticides from the same insecticide group code. trailer
Methamidophos: Other names/ Synonyms: Metamidophos: CAS-No. When insects eat acephate, their bodies turn it into a chemical called methamidophos, which is another, stronger insecticide. In soil, plants, and insects, acephate is converted to methamidophos. CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name MONITOR® 4 LIQUID INSECTICIDE MSDS Number 102000017045 EPA Registration No. No rapid reaction with air. /SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses./ Acephate and methamidophos affect the nervous system, causing over-activity in the nerves, muscles, or brain. 0000004147 00000 n
(Non-Specific -- Organophosphorus Pesticide, n.o.s.) 0000003178 00000 n
Trade name Methamidophos 585 SL INSECTICIDE. For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (1974). STOP – Read the label before use. 0000016229 00000 n
Alternate or tank mix with products from different insecticide codes. KEEP OUT OF REACH OF CHILDREN DANGER POISON PELIGRO Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. Organophosphate insecticides, including methamidophos, July 2004 – Worker Health & Safety Activities Following Methamidophos Drift Incident In Kern County (Project 0405) (PDF) Administer atropine PRECAUTIONS AND RESTRICTIONS Do not allow … 0000008924 00000 n
It is a mixed diacylamine, a phosphoramide, an organic thiophosphate and an organothiophosphate insecticide.It derives from a member of methamidophos. Methamidophos is an insecticide which no longer has approval for use in the EU. Excretion in the urine is the major elimination pathway. Signs and Symptoms of Acute Methamidophos Exposure: Acute exposure to methamidophos may produce the following signs and symptoms: pinpoint pupils, blurred vision, headache, dizziness, muscle spasms, and profound weakness. xref
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METAMIDOFOS 585 SL is a group code 1B insecticide. Signs and Symptoms of Acute Methamidophos Exposure: Acute exposure to methamidophos may produce the following signs and symptoms: pinpoint pupils, blurred vision, headache, dizziness, muscle spasms, and profound weakness. 0000006255 00000 n
SL or any other group 1A insecticide. 0000002647 00000 n
Dike fire control water for later disposal; do not scatter the material. Fight fire from maximum distance. 36 20
264-729 Bayer CropScience 2 T.W. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. including trade names and synonyms. 0000003412 00000 n
(EPA, 1998), This material is harmful or fatal if swallowed, inhaled, or absorbed through the skin. <]>>
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e待t�=}�W�dL �킵��+%E8o旽�Ys竹� [m����c��莎>+儀�ドoM칡�KeX���`��|5^K菰�w�痒��M"��*2�33; ���c$�j-`[Ξ�2粳4�N�=�_諄淃�A�K寂x����+첫%T쪄�Y�Q徑�ⅷ^K�ど�9��축E쟐,^/秘5��b����_食� n���c�繇 National Ocean Service, LABEL Malathion 5EC Insecticide / Miticide 217MSP-0115* MALATHION 5EC Page 1 of 15 Manufactured By: Drexel Chemical Company P.O. startxref
(EPA, 1998). endstream
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Use Systemic insecticide and acaricide for the control of many insects and mites as indicated on the label. �,�g至8纛������糟�#K^�蝟謠�p義�G�嫁�jL&���@�+V*�S3���z�
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Besiege insecticide, Brigade 2EC insecticide/miticide and Warrior II insecticide are Restricted Use Pesticides. x�b```"�|의� Crystalline solid, technical product is off-white with a pungent odor. Studies on the fate of the insecticide 32p-methamidophos (thiophosphoric acid-0,S-dimethylester amide) in a terrestrial laboratory micro-ecosystem model]. (EPA, 1998). For MEDICAL And TRANSPORTATION Emergencies ONLY Call 24 Hours A Day 1-800-334-7577 June 2005 – Risk Characterization Document (PDF) January 2005 – ; Exposure Assessment Document (PDF) Other Documents. • Residential risks are not of concern because methamidophos is not registered for use in residential settings. 撚b5h=+�R9說�_�o�����$�(��U�&������!��종gFZ줍fs=2H����S}�s묻���r�冥��.�`�gT、����{�E�uI���鏶≡L'�t晤����jぜj����"%��|�sF�MM��F������c�b�f寀� Cholinesterase inhibition results in stimulation of the central nervous system, the parasympathetic nervous system and the somatic motor nerves. Organophosphates, such as METHAMIDOPHOS, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. If symptoms of organophosphate poisoning are present, the administration of atropine sulfate is indicated. (Non-Specific -- Organophosphorus Pesticide, n.o.s.)
jJ�� �뿡�0� Methamidophos 10265-92-6 TWA a OSHA PEL b: None ACGIH ® TLV ®c: None NIOSH REL d: None NA 48 Only the identities of the active ingredient(s) and any hazardous inert ingredients are listed. Note: Methamidophos is a cholinesterase inhibitor. REGULATORY STATUS: Methamidophos is classified by EPA as a Class I compound, and must bear the signal word Pesticides in this toxicity class are restricted use pesticides (RUP). 0000004223 00000 n
It would not normally be expected to be persistent in soil or water systems. 0
DIRECTIONS FOR USE: IT IS AN OFFENCE TO USE THIS PRODUCT OFF-LABEL. For tank mixing or alternation with products in other insecticide group codes, refer to applicable product labels. Methamidophos is an organophosphate insecticide registered for use in the U.S. in 1972, and all uses were voluntarily cancelled in 2009 (U.S. EPA, 2009). Methamidophos, trade name "Monitor," is an organophosphate insecticide. Do not touch spilled material; stop leak if you can do so without risk. Always read and follow label directions, precautions and restrictions for use.Some products may not be registered for sale or use in all states. The selection of an individual tolerance level is based on crop field residue studies designed to produce the maximum residues under the existing or proposed product label. 0000000696 00000 n
Methamidophos is another organophosphate insecticide that is registered by the U.S. EPA. Wear positive pressure breathing apparatus and special protective clothing. In plants Methamidophos is an insecticide with systemic activity (Werner, 1972). Methamidophos is a metabolite of acephate, which had numerous residential, recreational, and institutional uses that were evaluated and mitigated through the Acephate IRED. View MSDS: EDB MO: Insecticide 1800 g/l: EDB halogenated organic: L4431: Soil View Product Label: No product brochure found in our online database. H�TP=O�0鳳+��`㉩|�梔�-��백�O�1���>拂縝=w��w또�'퓔��-�'Op腦�M{W��M��焄$�;4��y�$渣f全�-�7v����潗b漱�d%���t�O�vp�Dc�
M�R�O�Q���河��砧�8떫捻y{���t�aW�l�^��種�bQ+!~ 飾j� 1 Acephate has a strong odor similar to mercaptan, which smells like sulfur. Belongs to the Following Reactive Group(s). It is highly soluble in water and many organic solvents, and is volatile. 36 0 obj <>
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The oral doses of methamidophos that resulted in the mortality of half of the test organisms (LD50 values) are 21 and 16 mg/kg body weight for male and female rats respectively, 30-50 mg/kg body weight in guinea pigs and 10-30 mg/kg body weight in Stay upwind; keep out of low areas. 0000001346 00000 n
COMPOSITION / INFORMATION ON INGREDIENTS Active ingredient Methamidophos Chemical Name O,S-dimethyl phosphoramidothioate Methamidophos is highly toxic to mammals, and … Container may explode in heat of fire. FOLIMAT 20L FRONT LABEL – SIZE: 180 (W) X 190 (D) – COLOURS: BLACK, PMS 389, PMS 281 DATE: 10/06/14 DANGEROUS POISON KEEP OUT OF REACH OF CHILDREN READ SAFETY DIRECTIONS BEFORE OPENING OR USING GROUP 1B INSECTICIDE ACTIVE CONSTITUENT: 800 g/L OMETHOATE (an anti-cholinesterase compound) For control of certain pests on cotton, apples, … Any insect population may contain individuals naturally resistant to METAMIDOFOS 585 SL and other group code 1B insecticides. The methylating capability of methamidophos, assayed by the formation of [7-14C]methylguanine in mouse liver, was investigated using a 14C-insecticide labelled at the O--CH3 group. It has a role as an acaricide, an EC 3.1.1.7 (acetylcholinesterase) inhibitor and an agrochemical. (If you do not understand the label, find someone to explain it to you in detail.) Acephate is less toxic in mammals because mammal bodies do not turn it into methamidophos very well. Fire and runoff from fire control water may produce irritating or poisonous gases. Methamidophos is a potent acetylcholinesterase inhibitor. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration, METHYL PHOSPHORAMIDOTHIOATE ((MEO)(MES)P(O)(NH2)), PHOSPHORAMIDOTHIOIC ACID, O,S-DIMETHYL ESTER. H��W���H쏢yC!�T�nl┗�'�6x/�=� ��U��a鋌全�o��*I��&b�0�-십�z伉儼塹���}\���V�^6� �2F 0000016000 00000 n
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Methamidophos is also a breakdown product of the organophosphate insecticide acephate (Orthene) (157, 158). Methamidophos is an organophosphate which was patented by Bayer in 1965 and Chevron in 1967, for the control of insects and mites in a range of vegetable crops. Web site owner: methamidophos are likely to be lower than estimated. Methamidophos is toxic Methamidophos is an organophosphate that is an active ingredient in some insecticides to control thrips and tomato/potato psyllid. Use water spray to reduce vapors. 0000000994 00000 n
slurred speech, loss of reflexes are some of the central nervous 2. Move containers from fire area if you can do it without risk. Methamidophos is water soluble and had a moderate potential for runoff into surface waters, … This section provides a listing of alternate names for this chemical, Stay upwind; keep out of low areas. �CA;�a�)�O卨.FW��=�C�{�5�1涉���^�)4[れ6瑕!�(�9牲桓�Hr;�{x�j참N3i �v�公먕'��J�味beK亢�������Gt�v�p벽��\jK+�Y�
,$"�xl⒴�Yz���A梓$*S立�]�nW깔愚U驩2E��Et딨Xu�&택 G0�剡e�.�f�g�$L흩�h�O�@룹X�o恃貶�v텔棕]�o�E�Mex�j�,�j�3uA�e��e���eY�l晁��랗��hhS�y�K��q�F�C\�e%B�gf�z�R臻>���j]Y漲E���E㏇0�ko�Z±Y-�Je顚�Y壅B�;��,늬�귁~�к��C$죙��Q�돠�\Ju[���'�G�M渲.vWE싻�j�!NI�ZE$��xz�]�vi뱍4�i6훔X��v|x堵昔��S��eK�岫U�_�8�LHKo^���{"$��q��pH=L�lN� 1 Physical / Chemical Properties: Technical grade acephate is a white or transparent solid. Vomiting, diarrhea, abdominal pain, seizures, and coma may also occur. 55 0 obj<>stream
�R+-뼉�:ZS��묶y��� �O��Y&脊�lv��f怡K�f{(�IZ打'�}:*P��4�m�3京�. Avoid strong acids or alkalis. It is also used on nonfood crops such as alfalfa, clover, Bermuda grass, cut/outdoor flowers and in greenhouses. Vomiting, diarrhea, abdominal pain, seizures, and coma may also occur. Z Gesamte Hyg. 1. Risk Characterization Documents (RCDs) estimate the nature and likelihood of adverse health effects in humans who may be exposed to pesticides. The methamidophos, oxydemeton-methyl, and profenofos REDs and triclorfon TRED are found at http://www.epa.gov/ pesticides/ reregistration/ status.htm. The physical and chemical basis of systemic movement in the cotton plant was investigated by Hussain et al. Specific information on all of this product’s ingredients can be obtained by the treating medical professional or spill emergency responder for Methamidophos is a metabolite of acephate, which had numerous residential, recreational, and institutional uses that were evaluated and mitigated through the Acephate IRED. BOX 13327, MEMPHIS, TN 38113-0327 S I N C E 1 9 7 2. (EPA, 1998). Acephate is a phosphoramide that is methamidophos in which one of the hydrogens is replaced by an acetyl group. Following i.p. ��鋸p�!弗����i��S!�8北$K��?�oe}�N�=黔U㈒�k�Z+豈�Fη�)�) �@�|ij��MXqLNi�eG� Methamidophos is formed from biotransformation of another organophosphate insecticide, acephate. MSDS Number: 102000017045 MONITOR® 4 LIQUID INSECTICIDE MSDS Version 2.1 Revision Date: 05/23/2007 Page 1 of 8 SECTION 1. Note: Methamidophos is a cholinesterase inhibitor. No rapid reaction with water. (Non-Specific -- Phosphoramidothioic Acid, O-Ethyl S-Methyl Ester) Emits very toxic fumes of nitrogen oxides, phosphorus oxides, and sulfur oxides when heated to decomposition. 1985 Nov;31(11):644-6. Note: Methamidophos is a cholinesterase inhibitor. Ventilate closed spaces before entering them. insecticide, methamidophos, a cholinesterase inhibitor. 삡I�w��U����q��*��c�B���w�5補:_(2祀qtJ��*�E��JĿuM�C�\蚤e�� Methamidophos is fairly well distributed throughout the tissues, with marked accumulation in the liver, kidney, and adipose tissue. In the 14 C study (label = S-CH 3) absorption and a distribution was rapid.
administration of the toxicant, [7-14C]methylguanine could be … Post-mitigation risks for these uses, associated with the degradation of acephate to methamidophos, were evaluated in the Acephate IRED and found to be negligible. Click on the tabs for more information about the status of each phase in the review process. [Biological availability of methamidophos. (Non-Specific -- Organophosphorus Pesticide, n.o.s.) 0000003698 00000 n
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[EPA, 1998]. 0000003919 00000 n